Development of the Periodic Table

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Vinit Lotia                Teacher: Dr Dillip Joshi

TG: L108                Chemistry- October ‘04

Development of the Periodic Table

A necessary requirement to the building of the Periodic Table was the discovery of the individual elements themselves. Although elements such as gold, silver, tin, copper, lead and mercury have been known since antiquity, the first scientific discovery of an element occurred in 1649 when Hennig Brand discovered Phosphorous. During the next 200 years or so, a vast body of knowledge concerning the properties of elements and their compounds was founded by chemists. By 1869, a total of 63 elements, almost half of how many have been discovered today, had been discovered. As the number of known elements grew, scientists began to recognize patterns in properties and began to develop classification schemes into a displayable table, known as the Periodic Table.

Law of Triads:

In1817 Johann Dobereiner, a German chemist, noticed that the atomic weight of strontium fell midway between the weights of calcium and barium, elements having similar chemical properties. In 1829, after discovering the Halogen triad composed of chlorine, bromine, and iodine and the alkali metal triad of lithium, sodium and potassium he proposed that nature possessed triads of elements. The middle element of the triad had properties that were an average of the other two members when ordered by the atomic weight.

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This new idea of triads became a popular area of study. Between 1829 and 1858 a number of scientists (Jean Baptiste Dumas, Leopold Gmelin, Ernst Lenssen, Max von Pettenkofer, and J.P. Cooke) found that these types of chemical relationships extended beyond the triad. During this time fluorine was added to the halogen group; oxygen, sulphur, selenium and tellurium were grouped into a family while nitrogen, phosphorus, arsenic, antimony, and bismuth were classified as another. Unfortunately however, research in this area was halted by the fact that accurate and precise values of these elements were not always available.

First Periodic ...

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