The Modern Periodic Table
The Modern periodic table is closely based on Mendeleev’s table. All the gaps that he left have been filled as more and more new elements were discovered. A new group was established for the noble gases. Also the elements are now arranged in order of increasing atomic number, instead of atomic weight.
Gallium and Mendeleev’s Theory about Periodic Table
Mendeleev unlike previous scientists did not only produce a periodic table based on the elements that had been discovered at that time, but left gaps in his table for undiscovered elements. He named these undiscovered elements and predicted their properties in immense detail.
In 1875 a French scientist, Paul Emile Lecoq de Boisbaudran, discovered a new element that he named gallium. One of the elements that Mendeleev predicted was named eka-aluminium (as it was placed below aluminium in Mendeleev’s periodic table) and amazingly this new element gallium shared near identical properties to Mendeleev’s eka-aluminium. Mendeleev’s idea about the periodic table was given an enormous boost by this discovery. Over the next ten years two more of Mendeleev’s predicted elements were discovered; scandium (predicted by Mendeleev as eka-boron) and germanium (predicted as eka-silicon).
Unusual Properties of Gallium:
Gallium has three intriguing physical properties. Firstly, gallium’s melting point is 29.78°C, which is only slightly above UK room temperature. This makes gallium a liquid at room temperatures in areas which are hotter than the UK. Secondly, gallium has an extremely high boiling point of 2403°. So when comparing gallium’s melting point and boiling point it is clear that gallium has the widest liquid range compared to any other element. Thirdly, is that gallium shares the unique property of water by being denser as a liquid than as a solid. Presumably solid gallium has a more open structure than liquid gallium.
Gallium, Metal or Non-metal?
Gallium has chemical properties that resemble properties of metals, similar to that of aluminium. It dissolves in both acids and alkalis, evolving hydrogen.
2Ga(s) + 6H+(aq) 2Ga +(aq) + 3H (g)
Figure 1 - Reaction of gallium with hydrogen ions
2Ga(s) + 2OH (aq) + 6H O(l) 2[Ga(OH) ] (aq) + 3H (g)
Figure 2 - Reaction of gallium with hydroxide ions
Gallium is one of very few metals which have amphoteric hydroxides (hydroxides that show both basic and acidic properties because they react with both acids and alkalis). However gallium does also have properties that resemble non-metals. For instance, Gallium has a structure extremely similar to the non-metal iodine. Iodine and gallium both have a similar orthorhombic structure. Gallium is also a semi-conductor.
From Discovering Elements to Synthesising Elements
The UNILAC accelerator
The UNILAC accelerator works by firing a beam of relatively heavy ions from an accelerator towards a rotating disc of the target (a heavy, stable element such as lead). If done with sufficient violence, the ions overcome the natural repulsion of nuclei and fuse together, generating a new element. The new elements are then separated and detected.