I have applied this theory to my experiment because the reaction is taking place by collision and I am using less and less particles for each reading and so making the reaction take longer.
Method
I will begin by setting up my equipment, I will need a measuring cylinder, and a flask. I will keep the concentration of hydrochloric acid the same throughout the experiment and change the amount of sodium thiosulphate, this means I will only get one variable. The total volume of the solution will remain 55cm cubed throughout the experiment. I will achieve this by adding water to the solution. For example, when I add 5cm cubed of hydrochloric acid and 40cm cubed of sodium thiosulphate, I will add 10cm cubed of water so the concentration of the base actually changes.
I will first start by putting 5cm cubed of hydrochloric acid into the flask, I will then add 50cm cubed of sodium thiosulphate, I shall time how long it takes the solution to turn opaque. I will then repeat this with 40cm cubed of sodium thiosulphate and 10cm cubed of water to keep the volume at 55cm cubed. I will do this until I get down to 10cm cubed of sodium thiosulphate.
To get a good idea of the reaction time for each concentration I will repeat each experiment three times.
In order to keep the experiment, I will use separate measuring cylinders for the sodium thiosulphate and the hydrochloric acid, this will prevent contamination. I will also make sure that the flask is not moved or shaken when the reaction is taking place ensuring all reactions are fair.
Results
Here is a table of my results:
All of my results are correct apart from one, it is the last result for the 30cm cubed of sodium thiosulphate. It is much higher than any of the other results which means that it must be incorrect.
My results show that as less sodium thiosulphate is added, the reaction slows down.
Graph 1 shows my results.
Conclusion
As my results show, as less sodium thiosulphate is added, the reaction speed slows down. This is because there are fewer particles for the hydrochloric acid to collide with.
The reaction only happens because when the sodium thiosulphate particles collide with the hydrochloric acid particles, there is a reaction, this reaction creates sulphur. As there become less and less particles to collide with, the reaction takes longer to happen.