Rate of reaction of hydrochloric acid and mangesium ribbon.

Authors Avatar

Rate of rate of hydrochloric acid and mangesium ribbon

Introduction

In the reaction between hydrochloric acid and magnesium ribbon, the hydrochloric acid will dissolve the magnesium and produce hydrogen gas.

All chemical reactions involve reactants which when mixed may cause a chemical reaction which will make products.

In my case the reactants are hydrochloric acid and magnesium ribbon. The chemical reaction takes place when the magnesium ribbon is dropped into the hydrochloric acid. The products that are formed during this reaction are hydrogen gas and magnesium chloride. The formula equation for this experiment is:

Mg + 2HCl (r) MgCl2 + H2

Magnesium + Hydrochloric acid (r) Magnesium Chloride + Hydrogen

( s ) ( aq ) ( aq ) ( g )

Magnesium will react with hydrochloric acid, because it is higher in the reactivity series that hydrogen. When the two chemicals react a displacement reaction will take place and the magnesium will displace the hydrogen in the hydrochloric acid forming magnesium chloride and hydrogen gas.

Reactivity Series

K (potassium)

Na (sodium

Li (lithium) all to dangerous to react with a strong acid

Ba (barium)

Ca (Calcium)

..

Mg (magnesium) -

Al (aluminium) manageable metals

Zn (zinc) these metals will react with hydrochloric acid as they

Fe (iron) they are higher in the reactivity series than hydrogen

Sn (tin) and so a displacement reaction will take place

Pb (lead) ¯

..

H (hydrogen)

..

Cu (copper)

Hg (mercury) none of these metals will react with hydrochloric

Ag (silver) acid as they are all lower in the reactivity series than

Al (gold) hydrogen, therefore a displacement reaction will not

happen

Depending on certain factors the rate that this reaction will take place will either increase or decrease. The factors that may affect the rate of reaction are as follows:

· Temperature of the Hydrochloric Acid

· Mass of the magnesium ribbon used

· Concentration of the Hydrochloric acid

· Surface area of the magnesium ribbon used

All of these factors will change the rate of reaction because of the Collision Theory. This is a theory that is used to predict the rate of a reaction. The Collision Theory is based on the idea that for a chemical reaction to take place, it is necessary for the reacting particles to collide with each other with enough energy to break or form new bonds between the other particles, which is called a successful collision. If when they collide and they do not have enough energy to break or form new bonds then they will simple bounce of each other, causing an unsuccessful collision.

Ways that I could record my experiment

There are several way which I could record my experiment. The possible ways are as follows:

Amount of gas evolved

I could use a gas syringe to collect the gas that will evolve from my experiment. I could use these results to calculate the initial rate of reaction.

The weight before and after the experiment

I could put the conical flask with the chosen volume of hydrochloric acid onto a set of accurate electronic scales and record the weight of it. I could then drop a piece of magnesium into the conical flask and measure the decrease in weight at chosen intervals. The weight of the experiment will decrease because as the hydrogen in the hydrochloric acid is being displaced it is being released and will float up and out the conical flask, the weight change will not be very big, but there will be one.

How long the magnesium takes to dissolve

I could measure the length of time it takes for the magnesium to dissolve. The only problem with recording my experiment this way is that I could only calculate the average rate of reaction and not the initial rate of reaction

Ways to measure the rate of the reaction:

Average rate of reaction

Initial rate of reaction

I will be using the initial rate to calculate the rate of reaction as it can calculate the true rate and not the average rate of reaction.

Factors

The factors that could affect the rate of reaction of my experiment are as follows:

· Concentration of acid

This could affect the rate of reaction because the higher the concentration of the acid then the more acid particles per 100cm3 so more collisions per second and then there will be more successful collisions per second.

· Temperature of the acid

If the starting temperature of the acid is different each time the speed at which the acid particles collide with the magnesium ribbon will increase more the higher the temperature goes. This means the acid particles move with more energy, which means they will collide with the magnesium with more energy, which will give more successful collisions per second.

· Surface area of the magnesium

If the magnesium had a bigger surface area each time the experiment was done, then the acid particles will have a bigger area to collide with, so more collisions will occur every second and the more collisions per second than the more successful collisions per second.

· Type of acid used

If you changed the type of acid then the rate of reaction would change. Hydrochloric, Sulphuric and Nitric acid all would produce a different rate of reaction, so if I do change the type of acid then all three kinds would produce a different set of results.

Key factor

I have chosen to use the concentration of the acid as my factor that I will change. I chose this because several different concentrations can be made up before the experiment by the lab technicians and they will be able to make them accurately.

There will be several different concentrations of acid, which will give me a wide range of results, which will be reliable and reproducible.

Question

My question is to see that if I change the concentration of the Hydrochloric acid for each experiment I will see an increase or decrease in the rate of reaction between Hydrochloric acid and Magnesium ribbon.

Prediction

My prediction is that the higher the concentration of the acid then the higher the rate of the reaction will be. I am saying this because of the collision theory. The higher the concentration of acid then the higher the number of acid particles present per 100cm3 of acid. This means that there will be more collisions per second, which means there will be more successful collisions per second, so the rate of reaction will increase.

If I double the concentration of the acid from 1M hydrochloric acid to 2M hydrochloric acid then I will expect to see the rate of the reaction double. This is because there are twice as many acid particles in 2M hydrochloric acid than in 1M hydrochloric acid, so there will be twice the amount of collisions per second and because there are twice the amount of collisions per second then there will be twice as many successful collisions per second, increasing the rate of reaction.

Plan

I am intending to react a chosen length of magnesium ribbon with a chosen volume of hydrochloric acid. I will measure the rate of reaction by collecting the hydrogen gas that is produced in a gas syringe that will be connected, via a piece of rubber tubing and a rubber bung to the conical flask that the reaction will take place. I will quickly drop the length of magnesium into the flask and connect the rubber bung to it. I will then start the stop clock and record the volume of gas evolved every 5 seconds for 15 seconds. I have chosen these times because I only need three results as I am going to measure the initial rate of reaction and not the average. I will repeat each experiment so that my results are reliable and reproducible.

Fair Test

In order to keep my experiment a fair test I will have to make sure that I keep the following factors the same:

Join now!

· Starting temperature of the acid

· Volume of acid used (cubic centimetres)

· Surface area of the magnesium

· Clean the magnesium with emery paper before experiment

· Length of magnesium

I will also have to make sure that the gas syringe is correctly connected and that it is placed quickly and tightly enough so that no hydrogen gas escapes.

The following factor that I will change is:

· The concentration of the acid

Apparatus and chemicals used

The apparatus and chemicals used during my experiment are as follows:

Chemicals

· 1M hydrochloric acid

· 1.5M hydrochloric acid

· ...

This is a preview of the whole essay