The effect of surface area on the reaction rate between marble chips and hydrochloric acid.

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Bhaktipriya Nayan Kapadia- Chemistry coursework

Introduction: -

In this investigation I have a choice to change any variable too see what effects it could have. I am changing the Surface area to investigate which size particles are the fastest, and the quantity of gas (co2).

The other variables I could choose from to investigate are:

  •  The temperature of the acid
  •  The surface area of the test tube/flask
  •  Mass
  •  Concentration

Aim: -

I am investigating the affect of surface area on the rate of reaction between Hydrochloric acid and Marble chips of different sizes. I will be investigating which size of Marble chips will react the fastest with Hydrochloric acid.

Equations: -

          Marble +Hydrochloric                 Calcium  +carbon  + Water vapour

                 Chips         acid                    chloride    dioxide

          CaC03+ HCl               CaCl3 + CO3 + H20

Bhaktipriya Nayan Kapadia- Chemistry coursework 

Prediction and Background Science: -

I predict that the smaller the particles the faster the reaction. The reaction will be faster with smaller particles because it has a larger surface area, this means that the particles around the Marble chips in the solution will have more area to work on therefore more collisions will occur. The smaller the lumps the reaction can take place easily. Reactants only occur on surface of solid reactants. If a large lump is used,

There is not a lot of surface area on it. Breaking the lumps into smaller pieces increases the reactants to meet on, so more reacting particles can collide per second and the reaction will take place faster. The smaller the pieces the more surface area it has, whereas the larger the pieces have a smaller surface area. The equation for this experiment is:

Planning: -

I will do each experiment for 180 seconds. I will measure the surface area so I will use three different sizes of Marble Chips (small, medium and large). For each size of Marble chips I repeated the experiment twice and took an average, I measured the gas every 30 seconds.

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Preminary Study: -

I’ve tested using two molar Hydrochloric acid with Marble chips but I couldn’t even take the reading every

Bhaktipriya Nayan Kapadia- Chemistry coursework

Minute. The reason for this is that the concentration was too high. I then tried to use 5ml of Hydrochloric acid 5ml of water, which would decrease the concentration to one molar of Hydrochloric acid so then the reaction would be slower. This would mean I could take the reading every 30 seconds. This worked out in my trial so I obtained this for ...

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