The effect of temperature upon the rate of reaction between Sodium Thiosulphate and Hydrochloric acid.

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The effect of temperature upon the rate of reaction between Sodium Thiosulphate and Hydrochloric acid

Plan

I am going to be measuring the effect of temperature upon the rate of reaction between Sodium Thiosulphate and Hydrochloric acid. A yellow precipitate is produced in the reaction between the two chemicals in question.

 Na  S  O  (aq)             2HCl(aq)                  2NaCl(aq)           S(s)          SO  (g)         H  O

The rate of reaction can be seen by recording the time taken for a given amount of sulphur to be precipitated. I will do this by placing a conical flask containing the reaction mixture onto a cross on a piece of paper. As the precipitate of sulphur forms, the cross is obscured and finally disappears from view. The time taken for this to happen is a measure of the rate of reaction. To get enough information on the effect of changing the temperature of the reactants, several experiments must be done, using different temperatures of hydrochloric acid. To make this method safe I will be wearing goggles at all times to protect my eyes and I will thoroughly wash all my equipment with distilled water between each experiment to make it a fair test. I will also be using the same cross so that the density of the pen on the paper is not changed. I have also done some preliminary tests to determine what range of results to use. I used the random temperatures of 23 and 66°c and found that 20°c  was a good start but 66°c happened in too shorter time and meant that we could not take accurate readings due to human error. I have decided to use the range of 20, 30, 40, 50 and 60°c so that I get a good number of results and a range which will go through a lot of different points, I am not going past these limits as above 60°c it becomes too quick to accurately record it and below 20°c it becomes too slow to be of any use. I am also going to repeat this once more so that I get two sets of results and get a more accurate average and all readings will be to a hundredth of a second so to also make it more accurate. This will reduce the likeliness of getting anomalous results. I will be keeping the temperature of the Hydrochloric acid the same through out the experiment and only heating the Sodium Thiosulphate to the specified temperatures.

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Prediction

I predict that the rate of reaction will be fastest at high temperatures. When the temperature at which the reaction is carried out is increased, the energy that the particles hold also increases so the particles move faster. This means that there are more collisions between the Sodium Thiosulphate and Hydrochloric acid particles, and the collisions, which happen, are more violent and therefore more likely to react to form products. This means that if the temperature of the reaction is increased then the rate of reaction will increase.

Equipment

I am ...

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