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The Links Between CFCs And The Depletion Of Ozone In The Stratosphere, The Importance Of CFCs And The Search For Good Replacements.

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The Links Between CFCs And The Depletion Of Ozone In The Stratosphere, The Importance Of CFCs And The Search For Good Replacements There have been many methods to try and investigate the chemistry of the atmosphere. Some scientists use monitoring to find out what is present in the atmosphere and in what concentration. Many of the substances present have characteristic absoroptions in the infra-red and ultra-violet reigons of the spectrum. (1) Eg Ozone absorbss ultra-violet radiation with wavelengths below 360nm. (1) Ozone concentration has to be measured over a period of time, at different heights and lattitudes to make sure that any decreases are not from natural influences. This can be done from the ground, high-altitude planes and satellites. Laboratory measurements are used to determine how substances will behave in the stratosphere like how they are affected by solar radiation and the rates of reaction. The rate constants are very important and allows the rate to be calculated for almost any conditions. ...read more.


This was conclusive proof that a catalytic cycle involving Cl radicals must be involved in O3 depletion. Also figure 1 (4) shows a severe depletion in the ozone layer over the Antarctic on October 1, 1999. The rapid depletion of CFC's in the stratosphere is due to the high levels of ultra-violet radiation which leads to the photodissociation of CFC molecules. Eg A CFC 11 molecule would absorb the high energy ultra-violet radiation and fragment to release chlorine radicals: CCl3F ==> CCl2F + Cl. (1) The Cl radical could then destroy ozone in a catlytic cycle (1): Cl + O3 ==> ClO + O2 ClO + O ==> Cl + O2 ------------------------ overall: O + O3 ==> 2O2 (1) The chlorine atoms are not used up in these reactions, they are homogeneous catalysts. (4) The raction rate is fast and one chlorine molecule could destroy thousands of ozone molecules. The oxygen free radicals, O in the second equation, are formed continuosly in the stratosphere. ...read more.


CFCs have been used so widely for many reasons. It has the essential physical properties for a refigerent, appropriate boiling and freezing points (low enough to evapourate efficiently but high enough to liquefy by compression) (2). Its chemically stable, non toxic and cheap. (2) CFCs and the related HCFCs quickly became the refrigerantschioce for almost all applications. It had a wide range of uses, see table 2 below(2), and it was better than all previous refigerants. Table 2 (2) Compound Number Bp/ C Major Applications CCl3F CFC11 23 Air conditioners, water chillers, aerosols, coolant CCl2F2 CFC12 -29 Domestic fridges and freezers, car air condtioning, poly(styene) foams Scientists want to use HFC's (hydrofluorocarbons) as a replacement for CFC's because they contain fluorine as the only halogen (2). They also do far less damage to stratospheric ozone because HFC's are broken down in the troposphere by OH radicals so very little reaches the stratosphere also the C-F bond is not broken in the stratosphere. HFC's have no effect on O3 but they contribute to global warming. Also existing equipment will have to be modified or redesigned which could be very expensive. ...read more.

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