Atomic spectroscopy is one way which has been used to increase our knowledge about chemical elements. It excites atoms which then emit light; this light can be split by a prism which will show the ‘emission spectrum’. It is used widely to find the composition of a sample, such as blood, or to estimate the content of a substance.
“The sequence of lines in an atomic spectrum is characteristic of the atoms in the element.”*5
This technique was only discovered in the 1860’s, so was a very new method when Paul Emile Lecoq de Boisbaudran, 12 years later, in 1875, discovered a “faint violet line at 416 nm” on the spectrum of zinc sulphide ore. “Every element has it own characteristic set of lines. A new line (or lines) in a spectrum meant a new element.”*6
He called it Gallium, this new element had very similar properties to Mendeleev’s predicted element ‘eka-aluminium’; this therefore supported his idea of the Periodic table hugely.
Gallium has some very unusual properties, some which suggest that it is a metal and some that imply it is a non-metal.
Its physical properties, a melting point of 29.78°C (which is almost UK room temperature) making it a liquid metal along with Mercury and Caesium. It also has an extremely high boiling point, 2403°C; together with its low boiling point gallium has the ‘widest liquid range’ of any element discovered so far. Gallium is also denser as a liquid than as a solid, as is water.
Gallium’s chemical properties include, dissolving in acid and alkalis, evolving hydrogen. Aluminium and gallium both have the same reaction when mixed with hydrogen ions.
*8Reaction between aluminium and hydrogen ions
2Al(s) + 6H (aq) 2Al (aq) + 3H (g)
Reaction between gallium and hydrogen ions
2Ga(s) + 6H(aq) 2Ga (aq) + 3H (g)
The same happens in the reaction with gallium and hydroxide ions;
Gallium and hydroxide ions
2Ga(s) + 2OH (aq) + H2O(l) 2[Ga(OH) ] (aq) + 3H (g)
It also has dative covalent bonding due to the chloride empirical formula Ga Cl
The UNILAC accelerator has also been used to increase our knowledge and understanding of chemical elements. It wasn’t until the 1960’s after chemists and physicists had studied the atom that they realised it might be possible to create new elements. “…theoretical physicists pointed out that if the current picture of nuclear structure is correct, then there should be other higher ‘magic numbers’.”*10 Predicting that element 114 could be created and should be ‘magic’. Scientists look beyond the properties of the nuclei by looking at the range of isotopes available, “we refine the theoretical models of the properties of nuclei only by looking beyond the range of isotopes available to us on Earth and thereby taking into account the broadest possible spectrum of the nuclei present in the universe.”*11
Compared to the atomic spectroscopy this creates new artificial elements. “This involves firing a beam of relatively heavy ions from an accelerator toward a target of heavy, stable element such as lead.”*12
This technique was used by the GSI team in 1981, which fired a beam of chromium ions at a rotating target of bismuth metal. This resulted in the creation of element 107 – bohrium.
Cr + Bi element *13
The GSI formed four more elements over the following years; the most recent was February 1996, they fired zinc ions at a lead metal target, creating element 112 – ununbium.
Zn + Pb element *14
In the nineteenth century atomic spectroscopy was used commonly by scientists to discover new elements over 140 years of Mendeleev’s periodic table three of his predicted elements were discovered, eka-aluminium,
eka-boron and eka-silicon.
1875 – Paul Emile Lecoq de Boisbaudran discovered germanium, (eka-aluminium),
1881 – Lars Nilson found scandium, (eka-boron),
1886 Clemens Winkler found germanium, (eka-silicon).
Since then the UNILAC accelerator was introduced.
“There are 92 naturally occurring chemical elements”*15 from hydrogen to uranium. Scientists have gone beyond uranium by purposely synthesising ‘artificial’ elements; this is achieved using the UNILAC accelerator. This involves firing beams of metal ions into a rotating metal target with greater force, the nuclei of the atoms fuse together creating a new element.
In 1940, Ed McMillan created the first artificial element – Neptunium. Over the 25 years Glenn Seabory, of the University of California at Berkeley discovered an entire family of new elements, 94 to 102.
Specimen References:
*1-*3, *6-*9; Article 1 Gallium: a landmark in the history of chemistry
*4;
*5; Absorption Spectrum, page 125, SAC Chemical Ideas, George Burton et al, Heinemann, 2000.
*11 searched UNILAC accelerator
*12-*15; Article 2: The New Alchemist