Investigating the enthalpy of combustion

Authors Avatar

Prashant Pradhan YR 11

Chemistry HL – Enthalpy of combustion

Chemistry Lab report – Enthalpy of combustion

Aim: To see the trend in the combustion of the first five alkanols.

Introduction:

The standard enthalpy of combustion is the enthalpy change when one mole of a substance completely reacts with oxygen under standard thermodynamic conditions (although experimental values are usually obtained under different conditions and subsequently adjusted).

E.g. The standard enthalpy of combustion of ethane is the energy released when one mole of ethane is completely burned in excess oxygen under standard conditions. i.e. the energy change for the reaction:


C
2H6 + 3.5 O2  2CO2 + 3H2O

By definition, combustion reactions are generally strongly exothermic and so enthalpies of combustion are generally strongly negative.

It is commonly denoted as or

Enthalpies of combustion are typically measured using bond calorimetry, and have units of energy (typically kJ); strictly speaking, the enthalpy change per mole of substance combusted is the standard molar enthalpy of combustion (which typically would have units of kJ mol−1).

Join now!

Apparatus:

  1. 1 x Fuels – Methanol, Ethanol, Propanol, Butanol, and Pentanol.
  2. 1 x Tripod stand
  3. 1 x Beaker/ 100 cm3
  4. 1 x Beaker/ 500 cm3
  5. 1 x Digital thermometer/ oC (±0.01)
  6. 1 x Clay triangle
  7. 1 x Digital balance/g (±0.01)
  8. 1 x Measuring cylinder
  9. 1 x Matchbox
  10. Tissue paper

Method

  1. Using the measuring cylinder, measure out 25 cm3 of water and pour it into the 100 cm3 beaker.
  2. Place the clay triangle on the tripod stand and fit the 100 cm3 beaker into the ...

This is a preview of the whole essay