THE PREPARATION, ANALYSIS AND REACTIONS OF AN ETHANEDIOTE (OXALATE) COMPLEX IRON

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THE PREPARATION, ANALYSIS AND REACTIONS OF AN ETHANEDIOTE (OXALATE)         COMPLEX IRON

                                                                                            NAME: ADDISON JOSHUA HUGHES
                                                                                           ID: 1511907
                                                                                           EXPERIMENT: I.2.1.1.
                                                                                           DEMONSTRATOR: ADOLF OTI BOAKYE
                                                                                           DATE: 6
TH NOVEMBER, 2008.

AIMS

  1. To prepare a solution of ethanedioate (oxalate) complex iron.
  2. To analyze the amount of ethanedioate produced.
  3. To study the reactions that the oxalate complex iron undergoes.

INTRODUCTION

A coordination compound is any of a class of substances with chemical structures in which a central metal atom is surrounded by nonmetallic atoms or groups of atoms, called ligands, joined to it by chemical bonds. The metal atom in a coordination compound may be an electrically neutral atom or an ion. The ligands may also be neutral or charged. A ligand forms a chemical bond with the metal atom by sharing a pair of electrons with it. A ligand can attach to the atom by one bond (unidentate) or several bonds (multidentate). The oxalates of the alkali metals and of ferrous iron are soluble in water; all other oxalates are either insoluble or sparingly soluble in water. They are all rather soluble in dilute acids. The compound to be prepared is potassium tris(oxalato)ferrate(III) trihydrate. It is an octahedral transition metal complex in which three bidentate oxalate ions are bound to an iron centre. The general equation of the reaction is;

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(NH4)2[Fe(H2O)2(SO4)2]*4H2O + H2C2O4*2H2O                                 FeC2O4 + H2SO4 + (NH4)2SO4 +8H2O

H2C2O4*H2O + 2FeC2O4 + 3K2C2O4*H2O + H2O2                                  2K3[Fe (C2O4)3*3H2O + H2O

A titration with potassium permanganate (KMnO4) will then be used to determine the amount of metal in the oxalate complex. 

CHEMICALS AND APPARATUS

  1. Di Ammonium iron (II) sulphate
  2. 2M H2SO4 solution
  3. Potassium hydrogen oxalate
  4. 6% hydrogen peroxide solution
  5. Distilled water
  6. 0.02M permanganate solution
  7. Oxalic acid “ AnalaR”
  8. Mixture of ...

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