Obtain the IR spectra of several different paints and analyse them to identify pigment, polymer and binder bands, where possible.

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Rhiannon Edwards

220380

Infra Red Analysis of Paint

Objectives:

        The objective of this experiment was to obtain the IR spectra of several different paints and analyse them to identify pigment, polymer and binder bands, where possible.  

Then to obtain the IR spectra of three unknowns and identify which of the known paints they are by comparison.

Summary:

        

 

Method:

  1. Each known paint was placed into the IR spectrometer and the spectra obtained.
  2. The spectra of the three unknown paint samples were then placed in the IR spectrometer and their spectra obtained.
  3. The identity of the unknowns were then determined by analysis.

Results:

Identification of the Bands

Glixtone Fungi Matt Emulsion

        As you can see from the spectrum the broad peaks around 3400 and 1500 cm-1

and the sharp peaks at around 2900 and 1700 cm-1 are polymer bands and are characteristic of Nitrocellulose bands.  The peaks from 1200 – 450 are probably pigment bands.

B&Q Total Matt

        As you can see from the spectrum the broad peaks around 3500, 1500 and very broad peak around 1000 cm-1 and the sharp peaks at around 2900 and 1700 cm-1 are binder bands and are characteristic of an acrylic resin.  The peaks from 800 – 450 cm-1 are probably pigment bands, and identify kaolin.

Homebase Matt Vinyl Emulsion

        As you can see from the spectrum the broad peaks around 3500, 1500 and very broad peaks around 1500 and 1200cm-1 and the sharp peaks at around 2900 and 1700 cm-1 are polymer bands and are characteristic of polyurethane resin.  The peaks from 800 – 450 cm-1 are probably pigment bands, and identify Titanium dioxide.


Dulux Vinyl Matt

        As you can see from the spectrum the broad peaks around 3500 – 3000 and very broad peak around 1200 cm-1 and the sharp peaks at around 1700 cm-1 are polymer bands and are characteristic of polyurethane resin.  The peaks from 800 – 450 cm-1 are probably pigment bands, and identify Titantium dioxide.

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Dulux Non-Drip

        As you can see from the spectrum the broad peaks around 3500, 1500 and 1200 cm-1 and the sharp peaks at around 2900 and 1700 cm-1 are polymer bands and are characteristic of polyurethane resin.  The peaks from 800 – 450 cm-1 are probably pigment bands, but there is no distinct pattern.

Homebase Quick Drying Primer

        As you can see from the spectrum the broad peaks around 3500, 1500 and 1200 cm-1 and the sharp peaks at around 2900 and 1700 cm-1 are polymer bands and are characteristic of polyurethane resin.  The peaks from 800 – 450 ...

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