Identification of an organic unknown

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Identification of an organic unknown

Aim
In this piece of coursework I will be outlining a sequence of simple chemical tests to use to identify 8 different functional groups.

These functional groups I will be finding are, Alkene, primary alcohol, tertiary alcohol, aldehyde, ketone, carboxylic acid, ester and phenol.

I will be explaining the tests, the observations and the safety of each test/functional group.

Wet Tests

Bromine water
In the presence of an Alkene, the bromine water will turn the unknown from orange to colourless. C
2H4(L) + Br2(L)             C2H4Br2(L)
In the presence of a phenol group, a white precipitate will be formed when bromine water is added.
7
Phenol(L) + 3Br2(L)             2, 4, 6-tribromophenol(L) + 3HBr(L)

 1

2, 4 DPNH/Brady’s reagent
Add a few drops to Brady's reagent (2, 4-dinitrophenylhydrazine solution) to the unknown. Brady’s reagent detects the carbonyl function of an aldehyde and ketone. Yellow/orange precipitate forms with aldehyde or ketone.

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2
Tollens reagent
Warming tollens reagent with the organic unknown is a test for an aldehyde and ketone. Tollens reagent is an oxidising agent. When adding tollens reagent, an aldehyde will create a silver mirror on the side of the test tube.
In the presence of a ketone, no change will be made on the tollens reagent, as ketones cannot be oxidised.

3

Acidified potassium dichromate (VI)
Strong oxidising agent. Distil organic unknown with potassium dichromate (VI). If colour change happens from orange to green, the functional group has allowed the primary alcohol in the unknown to be oxidised.
 4

5

Phosphorus Pentachloride
PCL
5 is a ...

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