Plan and carry out an investigation to determine which of the four alcohols is the most exothermic.

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Joanna Lally 11B1        Chemistry GCSE Coursework

Comparing Heat Outputs Of Alcohols

By Joanna Lally 11B1

Brief

Plan and carry out an investigation to determine which of the four alcohols is the most exothermic.

Prediction

I predict that the most heat given out per mole burned would be by Propanol because the size of the alcohol molecules might increase with heat. Alcohols produce heat when they burn in oxygen or air. The amount of heat produced per mole of alcohol will be proportional to the amount of air present. Full combustion should generate two products only: carbon dioxide and water vapour.

Hypothesis

Within a molecule there are bond energies that are holding the atoms together. When the fuel combusts a chemical reaction takes place, this breaks the bonds, this requires energy, and makes new bonds this gives out energy. The energy differences between the two tell us how much energy was given out or taken in. We can show this on a graph. Alcohol particles will break their bonds when they mix with oxygen. This is known as exothermic reaction. Boiling points will be increased because energy is needed bonds can be formed and broken. Breaking bonds need less energy than is needed to form bonds – exothermic reaction. Bigger molecules use high energy to be broken. Methanol and Ethanol have differences as Methanol melts at a higher temperature and boils at a lower temperature than Ethanol. Higher alcohols which include Butanol and Propanol have a higher molecular weight and this is why Butanol is used in perfumes. Ethanol, which is sugar based, with its low freezing point, has a specific use as antifreeze for cars and other vehicles.

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Plan

Equipment: -        Brick                        Beaker                                Spirit Burner

                Thermometer                Clay Pipe Triangle                Measuring Cylinder

                Tripod                        Matches                        Goggles

Method: -        To begin with, I choose one out of the four different alcohols. I weigh beforehand in the spirit burner. This is so I can calculate the mass which is lost in each alcohol. The spirit burner and alcohol which I am using is on a brick under a tripod. On the tripod I place a clay pipe triangle which holds a beaker ...

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