What effect does temperature have on the rate of a reaction?

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Christopher Murphy 11DC Chemistry Mr Allison

What effect does temperature have on the rate of a reaction?

Aim of this reaction

To see the effects of a change in temperature and concentration on the rate of a reaction,

The reaction that will be used is:

Sodium Thiosulphate + Hydrochloric Acid
Na2S2O3 (aq) + 2HCl (aq)

Sodium Chloride + Water + Sulphur Dioxide +
2NaCl (aq) + H2O (l) + SO2 (g) + Sulphur S (s)

For my experiment I am going to change the temperature of the solution. When the temperature is being varied a water bath will be used to heat up the acid and thiosulphate to the necessary temperature.

The Chemistry

Some chemical reactions, such as explosions, happen very quickly while others like rusting, occur very slowly. The rate of reaction can be affected by a number of factors: temperature, concentration and pressure, adding a catalyst, surface area/particle size and light. The one that I am going to be investigating and explaining about is Temperature.
        Changes in temperature change the kinetic energy of the particles and hence the numbers of successful collisions with enough energy to break existing bonds.. The minimum energy needed for a successful collision is called the activation energy.
        For a reaction to take place molecules must collide with each other. When they do so, they must possess enough energy to cause or initiate a reaction. The level of energy needed to start a reaction is called its energy barrier. The actual energy needed to start a reaction is the activation energy e.g. a splint is needed to start a Bunsen burner in the process of combustion.
So in order to break the energy barrier, there has to be enough activation energy so the reaction will take place. Temperature helps to do this as increasing the temperature of the system increases the range of kinetic energies, increases the average kinetic energy and increases the population of particles with more than the activation energy
Reaction mixtures contain particles that have different amounts of energy. Some particles are of very high energy whilst others are of relatively low or medium energy. A graph can be produced to show these variations in energy and it is known as an energy distribution curve.

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Apparatus:

  • Sodium thiosulphate solution
  •  Hydrochloric acid
  • 250cm conical flask
  •  -5 C -110 C thermometer
  •  10cm /50cm measuring cylinder
  •  Stop clock
  •  Paper with a cross on it.

Prediction

As I explained earlier, the rate of a chemical reaction is the speed at which it takes place. Temperature is a major factor in this as increasing or decreasing the temperature changes the movement of particles in a substance therefore changing the rate of reaction. When a reaction mixture is heated up, each particle in it acquires more energy and collides more with other particles.  Thus, from my prior ...

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