Hous Process for producing Sodium Carbonate

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                  Hou’s Process for Sodium Carbonate

Introduction: 

  Hou’s process is developed based on Solvay process by Chinese chemist Debang Hou in 1930s; the first few steps are the same as the Solvay process. However, instead of treating the remaining solution with calcium carbonate (CaCO3), carbon dioxide (CO2) and ammonia (NH3) are pumped into the solution, then sodium chloride (NaCl) is added until the solution saturates at 40 °C. Next, the solution is cooled to 10 °C. Ammonium chloride (NH4Cl) precipitates and is removed by filtration, and the solution is recycled to produce more sodium carbonate (Na2CO3). (Source 2.)

The equation of Hou’s process is:

(1)NH3+H2O+CO2=NH4HCO3 

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(2)NH4HCO3+NaCl=NH4Cl+NaHCO3

(3)2NaHCO3=Na2CO3+H2O+CO2

NaCl (saturation) +NH3+H2O+CO2=NH4Cl+NaHCO3

2NaHCO3==Na2CO3+H2O+CO2

Compare the Solvay process and Hou’s process: (source 1.)

The advantage of Hou’s process is:

  Hou’s process kept the advantage of the Solvay process, but increased the yield from 90% to 96%. The Product ammonium chloride (NH4Cl) can be used as fertilizer, and can also be united with the production of ammonium. Hou’s process uses carbon monoxide (CO) to produce the required carbon dioxide (CO2) instead of using calcium carbonate (CaCO3). This eliminates the by-product calcium chloride (CaCl2) which is produced from the calcium carbonate (CaCO3) in the Solvay ...

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