A catalyst will not be used in this experiment, as this would affect the rate of reaction. This is because a catalyst provides a site for 2 molecules to meet and bond, thus speeding up the reaction.
The surface area is the last variable that will be kept constant throughout the experiment. If the surface area of the Magnesium strip is increased, this will cause an increase in the rate of reaction. This is because the larger the surface area, the more atoms there are for the particles to collide with. To keep the surface area constant, the Magnesium strips will be taken off the same roll and all measured to the same length. Also, the thickness of each strip will be checked using a micrometer to ensure that there is no increase or decrease in the surface area.
Apparatus -
Magnesium strips
Hydrochloric acid
Water
Conical flask
Bung
Water bath
Measuring cylinder
Stopwatch
Ruler
Method –
Measure strips of magnesium to 5cm using a ruler. Then check the thickness of each strip is equal using a micrometer
Use separate concentrations of acid. The concentrations used will be 0.4Molars, 0.8M, 1.2M, 1.6M AND 2.0M
Set out equipment as shown below
Make sure there are no gas bubbles at the top of the measuring cylinder
Put 1 strip of magnesium into the conical flask
Add 50ml exactly of the concentration of Hydrochloric acid
Cover conical flask with bung as quickly as possible
As the acid is poured in start the stopwatch.
Record the measurement (ml) from the conical flask every 20 seconds
Stop the experiment at the 3-minute mark on the stopwatch. Record the measurement at that time.
If the experiment seems finished before this time, i.e. when the measurement of hydrogen is not increasing, the timing may be cut short.
Also, if the opposite occurs, and the experiment is still reacting after 3 minutes, continue taking the experiment every 20 seconds, until you can be sure that the full reaction has taken place.
Repeat procedure for all concentrations of the Hydrochloric acid
Repeat any experiments with any anomalous results
The equation of the experiment is Mg + 2HCl = MgCl² + H²
In this experiment, you are measuring the amount of hydrogen collected at the top of the measuring cylinder.
Safety – All pupils should wear goggles during the entire experiment. This is because Hydrochloric acid is a highly corrosive substance. This can cause skin irritation if spilt on skin. The hydrochloric acid should also be kept well away from any open wounds. Also, anyone handling the Hydrochloric acid should wear protective gloves in case of any spillage.
Pilot study – A short pilot experiment was done in order to point out any flaws in the plan. The experiment was carried out for 3.30 minutes, with the results being taken every 30 seconds. For this experiment we used a concentration of 1Molar. The results are given below.
This pilot experiment caused me to make 2 changes to my original method. Firstly, I decided to cut the time of each experiment to 3 minutes, as I felt that this experiment showed that no more time was needed. However, this was again changed to accommodate experiments that took longer than the allotted time. Also, I decided to make the time between readings 20 seconds, as I felt that this would give us more accurate results and an improved graph.
Results – for Concentration of 2M
Concentration of 1.6M
Concentration of 1.2M
Concentration of 0.8M
Concentration of 0.4M
Observations – During the experiment, I noticed many interesting things. Firstly, as the strip of Magnesium was dropped into the acid, bubbles appeared around the strip. Also, as the reaction continued to occur, the strip shrunk in size. Eventually, the Magnesium strip had completely disappeared. This could be because the Magnesium was displacing the Hydrogen in the acid solution. When the Magnesium strip had disappeared, I noticed that the acid solution had turned slightly cloudy and grey in colour. The reaction also seemed to give off a bad smell. Most importantly however, I noticed that during the experiment, the temperature rose a small amount, showing that during the experiment, heat was given off.