Objective: The object of this lab is to show how temperature affects the conductivity (resistance) in various electrical materials and devices. Review of Scientific Principles: Heat: As heat is applied to a crystalline solid, we say "it gets hotter"; mean

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Temperature and Resistance of Electronic Materials

Objective: The object of this lab is to show how temperature affects the conductivity (resistance) in various electrical materials and devices.

Review of Scientific Principles:

Heat: As heat is applied to a crystalline solid, we say "it gets hotter"; meaning the temperature increases. On the atomic level, the kinetic energy of the atoms has increased which means the atoms are moving faster. However, in a crystalline solid, the atomic movement is limited to vibration around stable lattice positions. As the temperature increases, the atoms vibrate at a greater amplitude and move farther from their stable lattice positions. This motion has a negative effect on the ability of the material to conduct an electric current, causing it to have a greater electrical resistance.

Metals: In a metal, the valence electrons are thought of as being shared by all the positive ions. Therefore, the electrons are free to move throughout the crystalline lattice. The electrons move randomly throughout the crystal, until an electric field is applied to the material. Then the electric field forces the electrons to move in a direction opposite to the field. Actually, the electrons still move somewhat randomly, but with a superimposed "drift". This produces current. As the temperature increases, the positive ions in the crystal vibrate more, and more collisions occur between the valence electrons and the vibrating ions. These collisions hinder the "drift" motion of the valence electrons, thus reducing the current. In summary, for a metal, an increase in temperature causes an increase in resistance.

Semiconductors: In a semiconductor, at 0 K, valence electrons are in filled energy levels (bonds are formed by electron pairs filling the energy levels). They do not respond to an applied electric field to produce current flow. In the presence of an electric field, the electron motion is still random; no net motion in one direction occurs (no current flows). These filled energy levels, which the valence electrons occupy, form the valence band. In order for current to flow, electrons must move from the filled valence band to the empty conduction band. To make this move requires energy, which can be in the form of heat. (Important: the electrons do not move from a "place" in the crystal called the valence band to another "place" called the conduction band. The electrons have the energy associated with the valence band and acquire enough energy to have the energy associated with the conduction band. An energy change occurs, not a position change.) At room temperature, many electrons will have the energy needed to jump to the conduction band. As one electron moves out of the valence band and into the conduction band, a hole (vacancy) is produced in the valence band. Both the electrons in the conduction band and the corresponding holes in the valence band are considered charge carriers. When an electric field is applied to the material, these electrons and holes "drift". The electrons in the conduction band drift in the direction opposite to the applied field, and the holes drift in the same direction as the applied field. Thus, current is produced. As the temperature of the material is increased, more valence electrons acquire sufficient energy to move to the conduction band (producing holes), so more current flows. It is still true that as the temperature is increased, the atoms vibrate more and cause more collisions with the drifting electrons. However, this opposing effect is negligible, compared to the increase in charge carriers.

Applications:

Different types of materials respond differently to temperature changes. A computer engineer designing a circuit must be able to predict if the conductivity of each material in the device will be within an acceptable range over the expected temperature range of operation of the device.
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Time: One hour

Materials and Supplies:

heat source for boiling water (hot plate preferred)

5 beakers for water baths

thermometer

choke coils or resistance spools

germanium diodes

thermistors

light emitting diodes (LEDs)

carbon resistors

glass rod (5 cm)

2 digital multimeters or a voltmeter and milliammeter

wire connectors with alligator clips

power supply (0 to 12 volts DC)

General Safety Guidelines:

* The heat source could cause burns. ...

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