Testing for halide ions. The objective of the experiment was: Be able to identify halides using silver nitrate and ammonia.

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Activity: 15                          Chemistry practical                       Jaspreet Kaur, IB1

Testing for halide ions

Objectives:

 The objective of the experiment was:  

  • Be able to identify halides using silver nitrate and ammonia.

Equipment required:

Introduction:

A halide is a binary compound, of which one part is a halogen atom and the other part is an element or radical that is less electronegative (or more electropositive) than the halogen, to make a fluoride, chloride, bromide, iodide, or astatide compound. A halide ion is a halogen atom bearing a negative charge. The halide anions are fluoride (F-), chloride (Cl−), bromide (Br−), iodide (I−) and astatide (At−). Halide compounds such as KCl, KBr and KI can be tested with silver nitrate solution, AgNO3. The halogen will react with Ag+ and form a precipitate, with varying colour depending on the halogen. And, then by adding ammonia; the solution is acidified by adding dilute nitric acid. The nitric acid reacts with, and removes, other ions that might also give a confusing precipitate with silver nitrate.

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Procedure:

  • Potassium halides (potassium chloride, potassium bromide, potassium iodide) were placed into different three test tubes up to the height of 1ml.
  • Silver nitrate was added in all the three test tubes, containing potassium halides until a precipitate formed.
  • The colour of the three solutions was recorded.
  • Dilute ammonia(volume= 2*volume of potassium halides) was added in all the solutions, the stoppers were put on all the test tubes, and then the solutions were well shaked to dissolve them.
  • Concentrated ammonia was added in those solutions which did not dissolve but without stopper on the test ...

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